Direct covalent post-synthetic chemical modification of Cr-MIL-101 using nitrating acid†
Stephan Bernt,Vincent Guillerm,Christian Serre,Norbert Stock
Chemical Communications Pub Date : 01/21/2011 00:00:00 , DOI:10.1039/C0CC04526H
Abstract
For the first time, functionality has been covalently introduced into the Cr-MIL-101 network by post-synthetic modification of the terephthalate linker molecule through nitration. The nitro group was reduced and the amino group was reacted with ethyl isocyanate to yield the corresponding urea derivative.
