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Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene: electron deficiency compensation by asymmetric structural changes†
Madelyn Qin Yi Tay,Balasubramanian Murugesapandian,Yunpeng Lu,Rakesh Ganguly,Kinjo Rei,Dragoslav Vidović
Dalton Transactions Pub Date : 08/21/2014 00:00:00 , DOI:10.1039/C4DT01210K
Abstract

The synthesis, characterization and X-ray analysis of dichloro- and dibromo-borenium cations stabilized by a 4-membered carbene are reported. The ligand's structural changes, atypical for similar systems, were caused by coordination to electron deficient fragments and its CN2P ring strain.

Graphical abstract: Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene: electron deficiency compensation by asymmetric structural changes
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