A heteropentanuclear oxalato-bridged [ReIV4GdIII] complex: synthesis, crystal structure and magnetic properties†
José Martínez-Lillo,Laura Cañadillas-Delgado,Francesc Lloret,Miguel Julve,Juan Faus
Chemical Communications Pub Date : 07/26/2012 00:00:00 , DOI:10.1039/C2CC33350C
Abstract
The compound (NBu4)5[GdIII{ReIVBr4(μ-ox)}4(H2O)]·H2O (1), with intramolecular antiferromagnetic coupling, is the first Re(IV) system incorporating a 4f ion.
![Graphical abstract: A heteropentanuclear oxalato-bridged [ReIV4GdIII] complex: synthesis, crystal structure and magnetic properties](http://hg.y866.cn/compound/lib/scimg/usr/1/C2CC33350C.jpg)
