The electrochemical intramolecular cyclisation of propargyl 2-bromoethers 1–3 in N,N′-dimethylformamide at constant current in a diaphragmless cell has been developed using Ni^II complexes as electron-transfer mediators. During controlled-current electrolyses of solutions of Ni^II complexes in the presence of bromoethers, catalytic reduction of the latter proceeds via one-electron cleavage of the carbon–bromine bond to form a radical intermediate that undergoes cyclisation to afford the cyclic compounds in moderate to good yields.