Efficient strategy for interchangeable roles in a green and sustainable redox catalytic system: IL/PdII-decorated SBA-15 as a mesoporous nanocatalyst
Samira Sadeghi,Meghdad Karimi,Iman Radfar,Reza Ghahremani Gavinehroudi,Dariush Saberi,Akbar Heydari
New Journal of Chemistry Pub Date : 02/22/2021 00:00:00 , DOI:10.1039/D0NJ05459C
Abstract

Time and again, SBA-15-based composites as mesoporous materials and the incorporation of transition metals in them have been attracting dramatic attention in the field of catalysis due to their remarkable features. In this paper, the activity of SBA-15 supported ionic liquid–Pd(II) has been investigated in the catalytic transfer hydrogenation of nitroarenes with formic acid as a hydrogen donor at room temperature in water medium, and the oxidation of benzyl alcohols to benzaldehyde derivatives under atmospheric oxygen at high temperature. This novel nanocatalyst was characterized by FT-IR, SA-XRD, BET, BJH, TGA, FE-SEM, TEM, and ICP as the most commonplace techniques for analyzing its characteristics to be revealed as truth. Furthermore, the EDX analysis illustrates the grafting of the ionic liquid–Pd(II) into SBA-15. The catalyst showed high stability under reaction conditions, and can be recovered and reused for at least 15 and 6 reaction runs in oxidation and reduction reactions, respectively.

Graphical abstract: Efficient strategy for interchangeable roles in a green and sustainable redox catalytic system: IL/PdII-decorated SBA-15 as a mesoporous nanocatalyst