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Efficient visible light-mediated cross-dehydrogenative coupling reactions of tertiary amines catalyzed by a polymer-immobilized iridium-based photocatalyst†
Woo-Jin Yoo,Shū Kobayashi
Green Chemistry Pub Date : 02/05/2014 00:00:00 , DOI:10.1039/C4GC00058G
Abstract

The immobilization of an iridium-based heterogeneous photocatalyst via a radical polymerization process is described, and its catalytic activity was evaluated for the aerobic phosphonylation reaction of N-aryl tetrahydroisoquinolines under visible light irradiation.

Graphical abstract: Efficient visible light-mediated cross-dehydrogenative coupling reactions of tertiary amines catalyzed by a polymer-immobilized iridium-based photocatalyst
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