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Evolution of nano- to microsized spherical assemblies of fluorogenic biscalix[4]arenes into supramolecular organogels†
Chia-Chen Tsai,Kai-Chi Chang,I-Ting Ho,Jean-Ho Chu,Ying-Tsai Cheng,Li-Ching Shen,Wen-Sheng Chung
Chemical Communications Pub Date : 03/07/2013 00:00:00 , DOI:10.1039/C3CC40334C
Abstract

A biscalix[4]arene (1) capable of spontaneous self-assembly into nanoparticles and microspheres in CH3CN was serendipitously observed, and it eventually formed stable blue-light emitting supramolecular organogels.

Graphical abstract: Evolution of nano- to microsized spherical assemblies of fluorogenic biscalix[4]arenes into supramolecular organogels
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