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Diaza [1,4] Wittig-type rearrangement of N-allylic-N-Boc-hydrazines into γ-amino-N-Boc-enamines†
Eiji Tayama,Yoshiaki Kobayashi,Yuka Toma
Chemical Communications Pub Date : 08/01/2016 00:00:00 , DOI:10.1039/C6CC04626F
Abstract

Diaza [1,4] Wittig-type rearrangement of N-allylic-N-Boc-hydrazines into γ-amino-N-Boc-enamines was demonstrated. The scope and limitation, experimental mechanistic studies, and a proposed reaction mechanism were also described.

Graphical abstract: Diaza [1,4] Wittig-type rearrangement of N-allylic-N-Boc-hydrazines into γ-amino-N-Boc-enamines
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