Borophenes, which are two-dimensional boron counterparts made of the three synthetic polymorphs T, β₁₂ and χ₃, have been considered as potential anode materials in Li-ion batteries with extremely high capacities. However, Li hopping on β₁₂ and χ₃ borophenes is quite slow with high energy barriers (around 0.6 eV), thus preventing the application of these borophenes in the fast charging realm. Here, we have used halogen functionalization in an attempt to boost the sluggish Li-ion diffusion dynamics in the prototype χ₃ borophene system. Halogens bind strongly to χ₃ borophene with substantial electron transfer from the latter to the former, thereby leading to local electron deficiency in the χ₃ borophene. The synergy of electron extraction from χ₃ borophene and the electrostatic attraction between halogens and Li results in an enhanced affinity between χ₃ borophene and Li as well as a reduction in the Li-ion hopping barrier. Iodine is the preferred dopant, for which most diffusion paths exhibit energy barriers typically smaller than 0.2 eV. Our results suggest that halogen incorporation could facilitate intercalation and de-intercalation of Li-ions in borophene-based anode materials.