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Enhanced electroactivity and substrate affinity of microperoxidase-11 attached to pyrene-linkers π–π stacked on carbon nanostructure electrodes†
K. Sudhakara Prasad,Charuksha Walgama,Sadagopan Krishnan
RSC Advances Pub Date : 01/13/2015 00:00:00 , DOI:10.1039/C4RA14361B
Abstract

An exceptionally large electroactively connected microperoxidase-11 (MP-11) with strong affinity for organic peroxide and offering a high electrocatalytic reduction current density of 7.5 mA cm−2 is achieved for the first time. For this, MP-11 was attached via pyrene linkers on the surface of multiwalled carbon nanotube-modified graphite electrodes.

Graphical abstract: Enhanced electroactivity and substrate affinity of microperoxidase-11 attached to pyrene-linkers π–π stacked on carbon nanostructure electrodes
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