Electronic state and three-dimensional structure of Mn(iii) active sites in manganese-containing aluminophosphate molecular sieve catalysts for the oxyfunctionalisation of alkanes†
Furio Corà,Gopinathan Sankar,C. Richard A. Catlow,John Meurig Thomas
Chemical Communications Pub Date : 03/11/2002 00:00:00 , DOI:10.1039/B110017C
Abstract
Combined in situX-ray absorption spectroscopy measurements and quantum mechanical calculations yield a quantitative three-dimensional structure of the tetrahedrally coordinated Mn(III) active sites in MnAlPO catalysts.
