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A hydrolytically stable uranyl organic framework for highly sensitive and selective detection of Fe3+ in aqueous media†
Wei Liu,Jian Xie,Linmeng Zhang,Mark A. Silver,Shuao Wang
Dalton Transactions Pub Date : 11/28/2017 00:00:00 , DOI:10.1039/C7DT04365A
Abstract

We present a depleted uranium-based metal organic framework, UO2(C8H3O6N)·DMF, that exhibits highly sensitive and selective detection towards Fe3+ ions in aqueous media with an extremely low detection limit of 6.3 ppb. This work offers insight into exploring the potential applications of actinide-based metal organic frameworks in the area of chemical sensing with intrinsic advantages of high selectivity and sensitivity.

Graphical abstract: A hydrolytically stable uranyl organic framework for highly sensitive and selective detection of Fe3+ in aqueous media
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