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Enantiopure chiral coordination polymers of tetrahedral and octahedral cobalt(ii) alternate chains exhibiting slow magnetic relaxation behavior†
Dong-Rong Xiao,Guang-Ju Zhang,Jun-Liang Liu,Lin-Lin Fan,Ruo Yuan,Ming-Liang Tong
Dalton Transactions Pub Date : 04/28/2011 00:00:00 , DOI:10.1039/C1DT10262A
Abstract

The first two chiral homometallic coordination frameworks with homochiral helical [CoOctOTrpCoTdOTrp]n ferrimagnetic chains, exhibiting a unique coexistence of chirality and slow magnetic relaxation in one material, are reported.

Graphical abstract: Enantiopure chiral coordination polymers of tetrahedral and octahedral cobalt(ii) alternate chains exhibiting slow magnetic relaxation behavior
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