Exopericyclic stereocontrol in Johnson–Claisen rearrangements of allylic sulfides†
Donald Craig,John W. Harvey,Alexander G. O'Brien,Andrew J. P. White
Chemical Communications Pub Date : 08/23/2010 00:00:00 , DOI:10.1039/C0CC01039A
Abstract
A study of the effects of exopericyclic stereocentres on the stereoselectivity of Johnson–Claisen rearrangements of thioether-containing allylic alcohols shows that selectivity is highly dependent upon allylic substitution patterns.
