Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides†
Devendra J. Vyas,Martin Oestreich
Chemical Communications Pub Date : 12/11/2009 00:00:00 , DOI:10.1039/B920793G
Abstract
An unprecedented copper-catalysed allylic transposition enables the regioselective synthesis of branched allylic silanes from linear allylic halides through direct C–Si bond formation.
