Enantioselective epoxidation of olefins catalyzed by Mn (salen)/MCM-41 synthesized with a new anchoring method
Song Xiang,Yiliang Zhang,Qin Xin,Can Li
Chemical Communications Pub Date : 10/16/2002 00:00:00 , DOI:10.1039/B206104J
Abstract
New immobilization of the chiral Mn(salen) complex through the complexation of manganese by oxygen atoms of the phenoxyl groups grafted on the surface of MCM-41 leads to a markedly higher ee than for the free complex.