Enantioselective total synthesis of (+)-serinolamide A†‡,10.1039/C5RA06609C

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Enantioselective total synthesis of (+)-serinolamide A†‡

Suraksha Gahalawat,Satyendra Kumar Pandey

RSC Advances Pub Date : 04/29/2015 00:00:00 , DOI:10.1039/C5RA06609C

Abstract

A short and highly efficient enantioselective synthetic approach to (+)-serinolamide A 1 from racemic butadiene monoepoxide as a starting material is described. The synthesis utilizes the palladium catalyzed Trost's Dynamic Kinetic Asymmetric Transformation (DYKAT) and cross-metathesis (CM) as key steps.