Evidence of an equilibrium between selenides and osmium(viii) reagents and selenoxides and osmium(vi) reagents
Alain Krief,Alexandra Destree,Virginie Durisotti,Nicolas Moreau,Caroline Smal,Catherine Colaux-Castillo
Chemical Communications Pub Date : 02/15/2002 00:00:00 , DOI:10.1039/B109420N
Abstract

Driving the equilibrium between selenides and osmium(VIII) reagents with selenoxides and osmium(VI) by a subsequent reaction (rearrangement of allyl selenoxides to allyl alcohols or addition of osmium(VIII) species on C[double bond, length as m-dash]C double bonds) to one side, allows the transformation of methyl geranyl selenides to linalool and of methyl citronellyl selenoxide to 6,7-dihydroxy citronellyl selenide.

Graphical abstract: Evidence of an equilibrium between selenides and osmium(viii) reagents and selenoxides and osmium(vi) reagents