First stereoselective total synthesis of cryptomoscatone E1 and synthesis of (+)-goniothalamin via an asymmetric acetate aldol reaction†
Jhillu Singh Yadav,Dinesh Chandra Bhunia,Bogonda Ganganna,Vinay Kumar Singh
RSC Advances Pub Date : 03/01/2013 00:00:00 , DOI:10.1039/C3RA23167D
Abstract

A stereoselective total synthesis of (+)-goniothalamin and cryptomoscatone E1 have been described. The synthetic strategy involves an asymmetric acetate aldol reaction, Evans acetal intramolecular oxa-Michael reaction, ring-closing metathesis, Horner–Wadsworth–Emmons reaction and lactonization as the key steps.

Graphical abstract: First stereoselective total synthesis of cryptomoscatone E1 and synthesis of (+)-goniothalamin via an asymmetric acetate aldol reaction