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A hydroquinone based palladium catalyst for room temperature nitro reduction in water†
Alok Kumar,Kallol Purkait,Suman Kr. Dey,Amrita Sarkar,Arindam Mukherjee
RSC Advances Pub Date : 08/13/2014 00:00:00 , DOI:10.1039/C4RA06547F
Abstract

A hydroquinone based palladium complex [Pd(H2L)(Cl)2] (1), acts as an efficient room temperature catalyst for reduction of nitroarenes in water as solvent. 1 also acts as a tandem catalyst for Suzuki–Miyaura cross coupling in ethanol followed by reduction of nitroarenes in one pot with a loading of 0.25 mol% catalyst.

Graphical abstract: A hydroquinone based palladium catalyst for room temperature nitro reduction in water
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