An acceptor–donor–acceptor (A–D–A) triad based on a BODIPY acceptor and a benzodithiophene donor exhibited dual fluorescence and pronounced fluorescence solvatochromism because of twisted intramolecular charge transfer (TICT) state formation. Furthermore, it showed a Stokes shift of ∼194 nm which is the highest known for any BODIPY compound with a readily tunable fluorescence and a high charge carrier mobility of 4.46 × 10−4 cm2 V−1 s−1.
