Enhanced HOR catalytic activity of PGM-free catalysts in alkaline media: the electronic effect induced by different heteroatom doped carbon supports†,10.1039/C9TA01916B

热搜：

Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Enhanced HOR catalytic activity of PGM-free catalysts in alkaline media: the electronic effect induced by different heteroatom doped carbon supports†

Fulin Yang,Xi Bao,Yuanmeng Zhao,Xuewei Wang,Gongzhen Cheng,Wei Luo

Journal of Materials Chemistry A Pub Date : 04/12/2019 00:00:00 , DOI:10.1039/C9TA01916B

Abstract

A series of Ni-based catalysts consisting Ni nanoparticles and heteroatom (S, N, or B) doped carbon supports were constructed systematically, and further investigated to catalyze the hydrogen oxidation reaction (HOR) in alkaline electrolytes. The activity trend was found to follow the sequence of Ni/SC > Ni/NC > Ni/BC. Specifically, benefiting from the optimum anchoring effects and strong metal–support interaction, Ni/SC shows remarkable HOR catalytic performance, which is about 2.9 and 7.7 times higher than that of the dopant-free counterpart, Ni/C, in terms of specific activity and mass activity, respectively.