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A new avenue to the Dakin reaction in H2O2–WERSA†
Bishwajit Saikia,Parinita Borah
RSC Advances Pub Date : 12/03/2015 00:00:00 , DOI:10.1039/C5RA20133K
Abstract

We have developed a novel protocol to realize the Dakin reaction in a more greener way. In fact, by the use of H2O2–WERSA, we can oxidize aromatic arylaldehydes to phenols at room temperature. It is remarkable that the catalytic system does not require activation or any toxic ligand, additive/promoter, transition metal catalyst, base, organic solvent and so on. A range of substituted hydroxylated benzaldehydes were screened to investigate the scope of this protocol.

Graphical abstract: A new avenue to the Dakin reaction in H2O2–WERSA
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