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Effect of the allylic substituents on ring closing metathesis: the total synthesis of stagonolide B and 4-epi-stagonolide B†
Awadut G. Giri,Mohabul A. Mondal,Vedavati G. Puranik,Chepuri V. Ramana
Organic & Biomolecular Chemistry Pub Date : 10/29/2009 00:00:00 , DOI:10.1039/B916198H
Abstract

The total syntheses of stagonolide B and its 4-epimer were carried out to probe into how the relative stereochemistry of allylic hydroxy groups and their protecting groups influence the efficiency of the ring closing metathesis.

Graphical abstract: Effect of the allylic substituents on ring closing metathesis: the total synthesis of stagonolide B and 4-epi-stagonolide B
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