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Flaky nano-crystalline SnSe2 thin films for photoelectrochemical current generation†
Xiuyuan Shao,Dai-Ming Tang
RSC Advances Pub Date : 09/17/2018 00:00:00 , DOI:10.1039/C8RA04639E
Abstract

We report chemical vapor deposition (CVD) and photoelectrochemical properties of large-area thin films of nano-crystalline SnSe2 on conducting FTO glass. We show that densely packed, randomly oriented SnSe2 nanoflakes can be grown by reacting vapors of tin monoselenide (SnSe) and selenium at 550 °C without compromising the electrical properties of FTO. We demonstrate that SnSe2/FTO is photoelectrochemically active in visible to near-UV wavelengths (350–700 nm) and exhibits incident-photon-to-current-efficiency (IPCE) as high as 3.7% at 0 V versus the Ag/AgCl/1 M KCl reference electrode under 350 nm light illumination.

Graphical abstract: Flaky nano-crystalline SnSe2 thin films for photoelectrochemical current generation
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