[{Cp′Fe(μ-OH)}3]: the synthesis of a unique organometallic iron hydroxide†
Marc D. Walter,Peter S. White
Dalton Transactions Pub Date : 06/14/2012 00:00:00 , DOI:10.1039/C2DT31103H
Abstract
The synthesis of a novel trimeric iron(II) hydroxo complex stabilized by the sterically demanding 1,2,4-tri-tert-butyl-cyclopentadienyl ligand is reported. The high-spin iron(II) centres exhibit weak antiferromagnetic exchange coupling.