960化工网
A new family of boat-shaped Ln8 clusters exhibiting the magnetocaloric effect and slow magnetic relaxation†
Jia-Nian Li,Ning-Fang Li,Ji-Lei Wang,Xiao-Mei Liu,Qing-Dong Ping,Ting-Ting Zang,Hua Mei
Dalton Transactions Pub Date : 08/24/2021 00:00:00 , DOI:10.1039/D1DT02390J
Abstract

Designing and synthesizing lanthanide clusters have always been a research hotspot. Herein, three lanthanide clusters with the formula [Ln8(IN)143-OH)82-OH)2(H2O)8xH2O (Ln = 1-Gd and x = 11; Ln = 2-Dy and x = 8; Ln = 3-Eu and x = 8) have been isolated in the presence of isonicotinic acid under solvothermal conditions. Structural analysis indicates that those three compounds are isostructural, featuring boat-shaped {Ln8} metal frameworks. Magnetic measurements reveal that 1-Gd exhibits a larger MCE with the maximum −ΔSm value of 31.77 J kg−1 K−1 at 2 K for ΔH = 7 T, while 2-Dy displays slow magnetization relaxation. Besides, the photoluminescence properties of 3-Eu were investigated.

Graphical abstract: A new family of boat-shaped Ln8 clusters exhibiting the magnetocaloric effect and slow magnetic relaxation
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