First regioselective cyclometalation reactions of cobalt in arylketones: C–H versus C–F activation†
Robert Beck,Ulrich Flörke,Hans-Friedrich Klein
Dalton Transactions Pub Date : 09/05/2008 00:00:00 , DOI:10.1039/B813419G
Abstract
Phenylketones react smoothly under mild conditions with low valent cobalt(I) adducts to form new and stable five-membered cobaltacycles via C–H and C–F activation.
