Fluorous tagging of DABCO through halogen bonding: recyclable catalyst for the Morita–Baylis–Hillman reaction†‡,10.1039/C1CC10869G

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Fluorous tagging of DABCO through halogen bonding: recyclable catalyst for the Morita–Baylis–Hillman reaction†‡

Sophie Dordonne,Benoit Crousse,Danièle Bonnet-Delpon,Julien Legros

Chemical Communications Pub Date : 04/15/2011 00:00:00 , DOI:10.1039/C1CC10869G

Abstract

The halogen-bonded adduct between DABCO and two molecules of perfluorooctyl iodide (DABCO·(C₈F₁₇I)₂) acts as a recyclable organocatalyst for the Morita–Baylis–Hillman reaction. This “supramolecular fluorous catalyst” is readily accessible and can be recovered by simple precipitation/filtration.