A mesoporous ruthenium silica hybrid aerogel with outstanding catalytic properties in the synthesis of N,N-diethylformamide from CO2, H2 and diethylamine,10.1039/A906956I

热搜：

Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

A mesoporous ruthenium silica hybrid aerogel with outstanding catalytic properties in the synthesis of N,N-diethylformamide from CO2, H2 and diethylamine

Chemical Communications Pub Date : 01/01/1900 00:00:00 , DOI:10.1039/A906956I

Abstract

A mesoporous ruthenium silica hybrid aerogel containing well dispersed bidentate RuCl₂[Ph₂P(CH₂)₃PPh₂]₂ complexes, synthesized using a sol–gel method, affords turnover frequencies up to 18400 h^–1 and 100% selectivity from CO₂, H₂ and diethylamine for the formation of N,N-diethylformamide.