Functionalization of fullerene at room temperature: toward new carbon vectors with improved physicochemical properties†,10.1039/C6RA23419D

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Functionalization of fullerene at room temperature: toward new carbon vectors with improved physicochemical properties†

Z. Beiranvand,A. Kakanejadifard,A. Faghani,Z. Tu,A. Lippitz,F. Maschietto,B. Paulus,W. E. S. Unger,R. Haag

RSC Advances Pub Date : 11/23/2016 00:00:00 , DOI:10.1039/C6RA23419D

Abstract

In this work, fullerene has been functionalized with cyanuric chloride at room temperature by a nitrene mediated [2 + 1] cycloaddition reaction. The adduct after functionalization is inherently in the form of azafulleroid and shows broad UV absorption in the wavelength range of 200–800 nm, as well as photothermal conversion and fluorescence with a high quantum yield.