The synthesis of two novel gold(I) complexes with a phosphinine ligand is reported. Reaction of a monodentate phosphinine ligand, 2,6-diphenyl-4-methylphosphorin (L_p; 1), with gold(I) molecular bricks leads to the preparation of two new mononuclear complexes with the general formulae [AuCl(L_p)] (2) and [Au(L_p)₂](OTf) (3). The new compounds were spectroscopically characterized by infrared and NMR (¹H, ¹³C and ³¹P). In addition, the molecular structure of [AuCl(L_p)] (2) was unequivocally ascertained by a single-crystal X-ray diffraction study. Furthermore the UV-Vis absorption and emission properties of these compounds were investigated. These complexes pave the way for the synthesis of a new class of phosphinine gold complexes displaying peculiar properties, which might hold promise as luminescent materials.