From metal to ligand electroactivity in nickel(ii) oxamato complexes†
Xavier Ottenwaelder,Rafael Ruiz-García,Geneviève Blondin,Rosa Carasco,Joan Cano,Doris Lexa,Yves Journaux,Ally Aukauloo
Abstract
The locus of oxidation in square-planar nickel(II) oxamato complexes can be continuously shifted from the metal to the ligand by an appropriate choice of electron-donating substituents on the aromatic moiety of the ligand.
