Heterogeneous zirconia-supported ruthenium catalyst for highly selective hydrogenation of 5-hydroxymethyl-2-furaldehyde to 2,5-bis(hydroxymethyl)furans in various n-alcohol solvents†,10.1039/C6RA18016G

热搜：

Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Heterogeneous zirconia-supported ruthenium catalyst for highly selective hydrogenation of 5-hydroxymethyl-2-furaldehyde to 2,5-bis(hydroxymethyl)furans in various n-alcohol solvents†

Jusung Han,Yo-Han Kim,Hyung-Seok Jang,Sung-Yeon Hwang,Jonggeon Jegal,Jung Won Kim,Yoon-Sik Lee

RSC Advances Pub Date : 09/21/2016 00:00:00 , DOI:10.1039/C6RA18016G

Abstract

5-Hydroxymethyl-2-furaldehyde (HMF) was hydrogenated to 2,5-bis(hydroxymethyl)furan (BHMF) (>99% yield) in various n-alcohol solvents using a Ru(OH)_x/ZrO₂ catalyst. The TON and TOF for the hydrogenation were calculated to be 912 and 304 h⁻¹, respectively.