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Highly enantioselective cascade synthesis of spiropyrazolones†‡
Alex Zea,Andrea-Nekane R. Alba,Andrea Mazzanti,Albert Moyano
Organic & Biomolecular Chemistry Pub Date : 06/10/2011 00:00:00 , DOI:10.1039/C1OB05753G
Abstract

An efficient synthesis of spiropyrazolones based on organocatalysis is described. The reaction between pyrazolones, enolizable aldehydes and enals is catalyzed by secondary amine catalysts and affords the final spiro compounds bearing four contiguous chiral centers in good yields and excellent diastereo- and enantioselectivities.

Graphical abstract: Highly enantioselective cascade synthesis of spiropyrazolones
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