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Highly efficient, general hydrogenation of aldehydes catalyzed by PNP iron pincer complexes†
Thomas Zell,Yehoshoa Ben-David,David Milstein
Catalysis Science & Technology Pub Date : 11/26/2014 00:00:00 , DOI:10.1039/C4CY01501K
Abstract

A general protocol for the synthetically and industrially important hydrogenation of aldehydes to alcohols is reported. The reactions are catalyzed by well-defined iron pincer complexes that are capable of hydrogenation of aliphatic and aromatic aldehydes selectively and efficiently under mild conditions, with unprecedented turnover numbers.

Graphical abstract: Highly efficient, general hydrogenation of aldehydes catalyzed by PNP iron pincer complexes
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