As a widely used antimicrobial agent in toothpastes and body washes for decades, triclosan (TCS) is causing great harm to the environment through wastewater. Herein, we used a two-electrode system to remove TCS comprising Co₃O₄ nanowires/carbon cloth (Co₃O₄ NWs/CC) as anode and CoP nanowires/carbon cloth (CoP NWs/CC) as cathode. At a constant current density of 10 mA cm⁻², the degradation efficiency for TCS is 95% in 60 min and it is transformed into important chemical raw materials, including phenol, 1,2-dihydroxybenzene, and 2-phenoxyphenol. Subsequently, hydrogen is generated on the CoP NWs/CC cathode with Faradaic efficiency of nearly 100%. The synergetic effect of the superhydrophilic surfaces of the Co₃O₄ NWs/CC anode and the CoP NWs/CC cathode as well as the superaerophobicity of the cathode assures full contact of the electrolyte solution and the active materials and high-efficiency generation of H₂ bubbles.