Imidazolium ionic liquid functionalized magnetic multiwalled carbon nanotubes (CNTs–Fe₃O₄–IL) were synthesized and the structure, morphology and properties of nanocomposites were investigated using different characterization techniques such as FT-IR, VSM, SEM, TEM, XRD, TGA and DTA. In order to synthesize CNT–Fe₃O₄–IL, magnetite supported on CNTs (CNT–Fe₃O₄) was modified with 1-methyl-3-(3-trimethoxysilylpropyl)-1H-imidazol-3-ium chloride. This nanocomposite was found to be an efficient organocatalyst for the synthesis of 2-amino-chromenes via a microwave-assisted multicomponent strategy in aqueous media. The attractive features of this simple method include easy isolation of products, milder and cleaner reaction conditions, higher yields and purity of the product and an easier work-up procedure. This heterogeneous catalyst was easily separated by simply applying an external magnetic field and the recyclable organocatalyst was reused several times without any significant loss of activity. A combination of the advantages of ionic liquids and magnetic solid support nanomaterials provides an environmentally benign procedure for carrying out catalytic processes.