Facile synthesis of novel lithium β-diketonate glyme adducts: the effect of molecular engineering on the thermal properties†
Nishant Peddagopu,Patrizia Rossi,Carmela Bonaccorso,Ausrine Bartasyte,Paola Paoli,Graziella Malandrino
Dalton Transactions Pub Date : 01/03/2020 00:00:00 , DOI:10.1039/C9DT04732H
Abstract

Novel adducts of lithium hexafluoroacetylacetonato {Li(hfa)} with polyethers (monoglyme = {CH3OCH2CH2OCH3}, diglyme = {CH3O(CH2CH2O)2CH3}, triglyme = {CH3O(CH2CH2O)3CH3} and tetraglyme {CH3O(CH2CH2O)4CH3} have been synthesized through a single step reaction and characterized by FT-IR spectroscopy, 1H, and 13C NMR, single crystal X-ray diffraction studies along with thermal analysis.

Graphical abstract: Facile synthesis of novel lithium β-diketonate glyme adducts: the effect of molecular engineering on the thermal properties