A nickel dimethyl glyoximato complex to form nickel based nanoparticles for electrocatalytic H2 production†,10.1039/C4CC05355A

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A nickel dimethyl glyoximato complex to form nickel based nanoparticles for electrocatalytic H2 production†

Stéphanie Cherdo,Sanae El Ghachtouli,Marie Sircoglou,François Brisset,Maylis Orio

Chemical Communications Pub Date : 09/10/2014 00:00:00 , DOI:10.1039/C4CC05355A

Abstract

We report on the electrochemical alteration of a nickel(II) bis-glyoximato complex into nickel-based nanoparticles at a glassy carbon electrode under acid reducing conditions. These particles show electrocatalytic activity towards hydrogen production at +410 mV compared to the bare glassy carbon electrode. Mechanistic insights are discussed based on DFT calculations.