Gas-phase synthesis of the rare-gas carbene cation ArCH2+ using doubly ionised bromomethane as a superelectrophilic reagent
Daniela Ascenzi,Paolo Tosi,Detlef Schröder
Chemical Communications Pub Date : 07/29/2008 00:00:00 , DOI:10.1039/B811115D
Abstract
The bimolecular reaction of mass-selected CH3Br2+/CH2BrH2+ dications with argon leads to the rare-gas carbene cation ArCH2+, which represents an example of a new kind of organo rare-gas compound.
