A new coupling reaction for the synthesis of ruthenium half-sandwich complexes with sterically demanding cyclopentadienyl ligands†,10.1039/B618712A

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

A new coupling reaction for the synthesis of ruthenium half-sandwich complexes with sterically demanding cyclopentadienyl ligands†

Sébastien Gauthier,Euro Solari,Barnali Dutta,Rosario Scopelliti,Kay Severin

Chemical Communications Pub Date : 02/09/2007 00:00:00 , DOI:10.1039/B618712A

Abstract

The reaction of RuCl₃(solv.)_n with tert-butylacetylene in methanol or ethanol leads to the formation of chloro-bridged half-sandwich complexes with sterically demanding cyclopentadienyl ligands, which are of high interest as starting materials for the synthesis of novel Ru catalysts.