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High energy Li-ion capacitors with conversion type Mn3O4 particulates anchored to few layer graphene as the negative electrode†
Mani Ulaganathan,Vanchiappan Aravindan,Wong Chui Ling,Qingyu Yan
Journal of Materials Chemistry A Pub Date : 08/25/2016 00:00:00 , DOI:10.1039/C6TA05944A
Abstract

We report the fabrication of high energy Li-ion capacitors (LICs) using conversion type Mn3O4 octahedrons anchored to few layer graphene (Mn3O4-G) as the negative electrode with activated carbon (AC) as the positive one. First, the Mn3O4-G composite is prepared via a hydrothermal approach using commercially available graphene nanosheets. Li-storage studies of both electrodes (AC and Mn3O4-G) are conducted in single electrode/half-cell configuration with metallic Li to assess the mass balance. Prior to the fabrication of LICs, Mn3O4-G is pre-lithiated in Swagelok fittings with Li and subsequently paired with the desired loading of AC. The AC/Mn3O4-G based LIC delivered a maximum energy density of ∼142 W h kg−1 with excellent cyclability of 9000 cycles with ∼80% retention. This result certainly provides new avenues for the development of high energy LICs using conversion type negative electrodes rather than traditional insertion type anodes.

Graphical abstract: High energy Li-ion capacitors with conversion type Mn3O4 particulates anchored to few layer graphene as the negative electrode
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