An efficient and reliable synthesis of 2,4,6-tris(2-fluoro-2,2-dinitroethoxy)-1,3,5-triazine (1) has been developed. The ether 1 was fully characterized by IR and multinuclear NMR spectroscopy, and X-ray crystal structure determinations. The compound exhibits good density, excellent thermal stability, and high performance, while impact sensitivities are comparable to TNT.