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A new hydrogen bonding motif involved in self-recognition in the solid state by functionalised macrocycles†
Lydia Brelot,Xiao-yu Cao,Jack Harrowfield,Jean-Marie Lehn,Kari Rissanen,Luca Russo
CrystEngComm Pub Date : 01/26/2011 00:00:00 , DOI:10.1039/C0CE00814A
Abstract

Self-recognition within the crystal lattices of three functionalised macrocycles results in the formation of arrays of remarkably similar hermaphroditic pairs of macrocycles. In the case of two of the macrocycles containing acylhydrazine substituents, a hitherto unknown recognition pattern is found in the interaction of the hydrazine moiety with crown-ether oxygen atoms.

Graphical abstract: A new hydrogen bonding motif involved in self-recognition in the solid state by functionalised macrocycles
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