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Indium(iii) halides as exceptionally active, water-tolerant catalysts for cationic polymerization of styrenics†
Marc Bompart,Jérôme Vergnaud,Henri Strub,Jean-François Carpentier
Polymer Chemistry Pub Date : 05/11/2011 00:00:00 , DOI:10.1039/C1PY00145K
Abstract

The (co)polymerization of styrenes, α-methylstyrene, and indene is efficiently promoted by InBr3 or InCl3, in combination with an alkyl halide. This convenient route employs unpurified (wet) monomers, proceeds at slightly higher than room temperatures, and uses amounts as low as 20 ppm of indium pre-catalyst.

Graphical abstract: Indium(iii) halides as exceptionally active, water-tolerant catalysts for cationic polymerization of styrenics
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