A new oximeligand in manganese chemistry: a [Mn8] and a [Mn6] cage from the use of 2-dihydroxy-2-phenylacetamidine†
Andreas G. Flamourakis,Demetrios Tzimopoulos,Milosz Siczek,Tadeusz Lis,James R. O'Brien,Pericles D. Akrivos,Constantinos J. Milios
Dalton Transactions Pub Date : 09/29/2011 00:00:00 , DOI:10.1039/C1DT11455G
Abstract
The use of phamidoxH2 (phamidoxH2 = 2-dihydroxy-2-phenylacetamidine) in manganese cluster chemistry led to the synthesis and characterization of a hexametallic and an octametallic MnIII cluster, both of which display a S = 3 ground state.