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Heterolytic H2 splitting across a Ru–S bond leading to the replacement of S by O in the carborane-dithiolato ligand of a 15-electron Ru(iii) complex†
Qibai Jiang,Zhaojin Wang,Yizhi Li,Hong Yan
Chemical Communications Pub Date : 05/13/2013 00:00:00 , DOI:10.1039/C3CC42554A
Abstract

A 15-electron Ru(III) complex containing carborane-thiolato ligands heterolytically cleaves dihydrogen at ambient pressure and temperature to give Ru(IV)/Ru(II) species containing a hydrido ligand at Ru(IV) and SH ligand at Ru(II). In the presence of HBF4·H2O the reaction further leads to an unprecedented replacement of an S atom by an O atom in the carborane-dithiolato ligand.

Graphical abstract: Heterolytic H2 splitting across a Ru–S bond leading to the replacement of S by O in the carborane-dithiolato ligand of a 15-electron Ru(iii) complex
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