A new entry to N-heterocyclic carbene chemistry: synthesis and characterisation of a triscarbene complex of thallium(i)†
Hidetaka Nakai,Yongjun Tang,Peter Gantzel,Karsten Meyer
Chemical Communications Pub Date : 11/26/2002 00:00:00 , DOI:10.1039/B209071F
Abstract

The synthesis and characterisation of a thallium(I) triscarbene complex of the chelating, tripodal carbene ligand 1,3,5-{tris(3-tert-butylimidazol-2-ylideno)methyl}-2,4,6-trimethylbenzene is reported, in which the thallium ion is coordinated by three N-heterocyclic carbene donors in a distorted trigonal planar environment.

Graphical abstract: A new entry to N-heterocyclic carbene chemistry: synthesis and characterisation of a triscarbene complex of thallium(i)