960化工网
Hydrothermally stable ZnAl2O4 nanocrystals with controlled surface structures for the design of long-lasting and highly active/selective PdZn catalysts†
Xian-Hua Zhang,Chang Liu,Congming Ke,Liang Liu,Xinning Hao,Yaping Wu,Shaolong Wan,Shuai Wang,Yong Wang
Green Chemistry Pub Date : 11/01/2019 00:00:00 , DOI:10.1039/C9GC02483B
Abstract

Hydrothermally stable ZnAl2O4 nanocrystals with controlled surfaces including Zn-rich and Al-rich structures are synthesized by a facile method. The Zn-rich surfaces are utilized to design long-lasting PdZn/ZnAl2O4 catalysts evaluated in the aqueous phase hydrogenolysis of glycerol for 10 consecutive cycles showing high activity and selectivity.

Graphical abstract: Hydrothermally stable ZnAl2O4 nanocrystals with controlled surface structures for the design of long-lasting and highly active/selective PdZn catalysts
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